Experiment 9:  SCANNING TUNNELLING MICROSCOPY OF SURFACES
 

Equipment:  Nanosurf scanning tunnelling microscopy, model Easyscan STM.  Specificationa and sample images are at  http://www.nanosurf.ch/.

Readings:  None.

Key concepts:  Atomic structure of surfaces; tunnelling.



Read the instructions and then carry out measurements to image surfaces of various materials provided.


Sample measurement of the surface of graphite..  Below are shown scans of graphite, whose crystal structure is hexagonal.  The images give the appearance of a triangular lattice, but this is only because half of the surface atoms image as bright spots and the other half as dim ones.
 


STM image of surface of graphite (measured in quantum lab)
 


Images from Nanosurf's web page with an explanation of the structure follow:

In a good top view image of graphite you will see a pattern consisting of white, grey and black spots. To interpret the image correctly: the bright spots mean higher tunneling current and dark spots mean low current.


scan size: 2.0 nm

Out of the lattice model of graphite one can see that there are two different positions of the carbon atoms in the graphite crystal lattice (see e.g. R.C. Tatar et al. Phys Rev B 25 (1982) 4126).
 

One with a neighbouring atom in the plane below (grey) and one without a neighbour in the lattice below (white). Consequently the electrical conductivity of the graphite surface varies locally slightly (different electronic density of states) so that the atoms without neighbours appear "higher" than the others (see e.g. I.P. Batra et al. Surf Sci 181 (1987) 126). This also causes the lattice constant between the bright ‘hills’ to have the higher value of 0.25nm than the nearest neighbour distance in the graphite lattice of 0.14nm.



Copyright Gary S. Collins, 2002.