Testing the Heat Flow Model

Initial Conditions

The simulation begins with 1,000 cc of water and an internal energy content of 9,000 calories. The internal energy content is defined relative to a base temperature of 10 degrees Celsius. The water temperature depends on the Internal Energy Concentration which is measured in calories per gram. At the start of the simulation, there are 9,000 calories evenly distributed over 1,000 grams, so the concentration is 9 calories per gram. The water temperature equation assumes that zero concentration corresponds to 10 degrees. The specific heat of water is 1 calorie per gram per degree. In other words, 1 calorie of heat is required to increase the temperature of a gram of water by 1 degree. Working from a base of 10 degrees, the energy concentration of 9 calories/gram means that the initial water temperature is 19 degrees.

The heat flow into the glass depends on TempDif, the difference between the air temperature and the water temperature which is 1 degree at the start of the simulation. The initial heat flow is around 1.4 calories/sec. But the heat loss due to evaporation is much smaller (only about 0.1 calories/sec). With more heat flowing in than flowing out, you would expect the internal energy content and the water temperature to increase.

Now, let's run the model over thousands of seconds to learn whether the water temperature will eventually reach 20 degrees.

Simulation Results

Figure 5 shows the simulated behavior over 60 minutes. The air temperature is constant at 20 degrees, and the water temperature increases over time. The heat flows are scaled from 0 to 2 calories/second. At the beginning of the simulation, the heat flowing in is around 1.4 calories/second while the heat loss due to evaporation is only around 0.1 calories/second. The net inflow is over 1 calorie/second. If these flows were to persist for 1,000 seconds, we would expect over 1,000 calories to be added to the energy content of the water--more than enough to increase the water temperature to 20 degrees. But the simulation shows that the temperature never reaches 20 degrees. After 15 minutes, for example, the water temperature is only up to around 19.7 degrees. There is still a temperature difference across the glass surface of 0.3 degrees. This means the heat flowing into the glass is much smaller.

Figure 5. Results for One Hour of Simulated Time.

By the 30th minute of the simulation, the heat flowing into the glass has declined almost to the same value as the heat loss from evaporation. The water temperature appears to be approaching 20 degrees after 30 minutes, but it is still not quite the same as the air temperature. By the 45th minute of the simulation, the heat flows in and out of the water are nearly equal. And the water temperature appears to be leveling off slightly below 20 degrees. By the end of the simulation, the water temperature is 19.92 degrees.

  We see a small temperature difference across the surface of the glass, and it isn't going away!

The size and persistence of this temperature difference is the focus of the introductory exercises.